Temporal changes in soil chemical and nutritional properties were evaluated in a long-term experiment conducted on Alfisols in West Africa. Effects of land use and cropping duration on soil chemical properties at 0–5 cm and 5–10 cm depths were evaluated for five treatments: (1) alley cropping with Leucaena leucocephala established on the contour at 4-m intervals; (2) mucuna (Mucuna utilis) fallowing for 1 year followed by maize (Zea mays)-cowpea (Vigna unguiculata) cultivation for 2 years on severely degraded land; (3) fallowing with mucuna on moderately degraded soils; (4) ley farming involving growing improved pastures for 1 year, grazing for the second year, and growing maize-cowpea for the third year on severely degraded land; (5) ley farming on moderately degraded soils. Soil chemical properties were measured once every year from 1982 through 1986 during the dry season, and included pH, soil organic carbon (SOC), total soil nitrogen (TSN), Bray-P, exchangeable cations, and effective cation exchange capacity (CEC). Regardless of the cropping system treatments, soil chemical quality decreased with cultivation time.