The organic matter of the surface horizons of soils developed below scrub vegetation in a Mediterranean semi-arid area of great environmental interest (Cabo de Gata-Níjar Natural Park, SE Spain) has been studied. The study mainly concentrates on examining the influence of two vegetation types, one evolved (according to its successional stage), and the other clearly degraded as a result of prior removal of vegetation. In spite of the homogeneity in the results obtained from the analysis of the organic matter from the soils studied, a relationship may be established between vegetation biotype and characteristics and evolution of the soil organic matter. The evolved vegetation results in the presence in the soil of a somewhat more evolved and stable organic matter (demonstrated by certain chemical and microbiological aspects), resulting in a greater degree of humification, thus favouring the protection of the soil and the ecosystem as a whole. Hence, the presence of degraded vegetation might lead to soil degradation, something that is unsustainable in semi-arid areas that are particularly fragile in nature.